\n7. Limited life arid low reliability.<\/td>\n | Long life and high reliability.<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n Classification Of Metals, Conductors, And Semiconductors<\/span> \n1. On the basis of conductivity: \nOn the basis of relative values of electrical conductivity (\u03c3) and resistivity \u03c1 = \\(\\frac{1}{\\sigma}\\) solids are classified as<\/p>\n(i) Metals: \nThey possess very low resistivity (or high conductivity). \n\u03c1 \u2192 10-2<\/sup> – 10-8<\/sup> \u2126 m \n\u03c3 \u2192 102<\/sup> – 108<\/sup> S m-1<\/sup><\/p>\n(ii) Semiconductor: \nThey have resistivity or conductivity intermediate to metals and insulators. \n\u03c1 \u2192 10-5<\/sup> – 106<\/sup> \u2126 m \n\u03c3 \u2192 105<\/sup> – 10-6<\/sup> S m-1<\/sup><\/p>\n(iii) Insulators: They have high resistivity (or low conductivity). \n\u03c1 \u2192 1011<\/sup> – 1019<\/sup> \u2126 m \n\u03c3 \u2192 10-11<\/sup> – 10-19<\/sup> S m-1<\/sup><\/p>\n2. Band Theory: Conduction Band, Valence Band, and Energy Gap: \nIn an isolated atom, electrons will have definite energy level. When atoms combine to form solid, the energy levels of outer electrons overlap. Hence outer energy levels split in to many energy levels.<\/p>\n These energy levels are very closely spaced Hence it appears as continuous variation of energy. This collection of energy levels are called energy band.<\/p>\n The energy band which includes energy levels of valence electrons is called valence band. The energy band above valence band which includes energy levels of conduction electrons is called conduction band.<\/p>\n The gap between the top of valence band and bottom of conduction band is called energy band gap (Energy gap, Eg<\/sub>). \nEnergy level diagram of different bands: \n \nThe band gap energy of Ge and Si are 0.3ev and 0.7ev respectively.<\/p>\n3. Classification on the basis of Energy bands Conductors: \nConduction band is partially filled and valence band is partially empty.<\/p>\n OR<\/p>\n Conduction band and valence band are overlapped so that Eg<\/sub> = 0ev \n \nDue to overlapping, electrons are partially filled in conduction band. These partially filled electrons are responsible for current conduction.<\/p>\nInsulators: \n \nConduction band is empty. Valence band may fully or partially filled. There is a wide energy gap between valence band and conduction band (Eg<\/sub> > 3ev).<\/p>\nSemiconductors: \nConduction band may be empty or lightly filled. Valence band is fully filled. The energy gap is very small (< 3ev) \n \nAt room temperature some electrons in valence band get enough energy to cross the energy gap and move into conduction. Hence semiconductors show intermediate conductivity.<\/p>\n Intrinsic Semiconductor<\/span> \nA semiconductor in its pure form is called intrinsic semiconductor.<\/p>\nFor intrinsic semiconductor: \n* The number of free electrons is equal to number of holes. \nie. ne<\/sub> = nh<\/sub> = ni<\/sub> \nne<\/sub>, nh<\/sub> and ni<\/sub> are the free electron concentration, hole concentration and intrinsic carrier concentration.<\/p>\nExplanation: \nEach Si atom is covalently bonded to nearest four neighboring atoms. When temperature increase, some of covalent bond brakes and electrons become free leaving a vacancy (hole). Thus each free electron creates hole in the lattice. Hence number of free electrons equals number of holes.<\/p>\n * The total current in intrinsic semi conductor is the sum of free electron current Ie<\/sub> and hole current Ih<\/sub>. \nI = Ie<\/sub> + Ih<\/sub><\/p>\nExplanation: \nWhen an electric field is applied, free electrons move towards positive potential and give rise to electron current, le. The holes move towards negative potential and give rise to hole current. Thus total current is contributed by both free electrons and holes.<\/p>\n Extrinsic Semiconductor<\/span> \n1. Extrinsic semiconductor or impurity semiconductor: \nThe addition of suitable impurity improves the conductivity of intrinsic semiconductors. Such semiconductors are called extrinsic semiconductor. They are of two types n-type and p-type semiconductors.<\/p>\n2. Doping and Dopants: \nThe deliberate addition of suitable impurity to semiconductors to improve its conductivity is called doping. \nThe impurity atoms are called dopants. There are two types of dopants;<\/p>\n \n- Pentavalent (valency 5): Arsenic (As), Antimony (Sb), Bismuth (Bi), Phosphorous (P), etc.<\/li>\n
- Trivalent (Valency 3): Indium (In), Boron (B), Aluminium (Al), etc.<\/li>\n<\/ul>\n
3. n-type semiconductor: \nWhen a pentavalent impurity is added to Si crystal, four electrons of impurity atom make bond with neighboring four Si atoms. The fifth electron remains weakly bound to its parent atom.<\/p>\n At room temperature this electron become free to move. Thus each pentavalent atom donate one extra electron for conduction and hence it is called donor impurity. \n \nThus in doped semiconductor the number of conduction electrons will be large compared to number of holes. Hence electrons are the majority carriers and holes the minority carriers. Hence semiconductors doped with pentavalent impurity is called n-type semiconductor. \nNote: \nIn n-type semiconductors \nne<\/sub> >> nh<\/sub> \nBut as a whole n-type semiconductor is neutral (ie. electrons is equal and opposite to ionized (donor) core in lattice).<\/p>\n4. p-type semiconductor: \nWhen a trivalent impurity is added to Si crystal, three electrons of impurity atom make covalent bond with neighboring three Si atom. The fourth bond with neighboring Si atom lacks one electron. Thus a vacancy or a hole is created in fourth bond.<\/p>\n The neighboring Si atom needs an electron to fill the vacancy and hence one electron in outer orbit of nearby Si atom move to this vacancy leaving a hole in its own site. Thus hole can move through the lattice.<\/p>\n Each trivalent atom creates a hole and it act as acceptor. Hence it is called acceptor impurity. The semiconductor doped with trivalent impurity has more number of holes than free electrons. Here holes are the majority carriers and electrons are the minority carriers. Hence it is called p-type semiconductor. \nNote: I \n(I) In p-type semi conductor \nnh<\/sub> >> ne<\/sub> \nBut as a whole p-type semiconductor is electrically neutral. (The charge of additional holes is equal and opposite to acceptor ions).<\/p>\n(II) In thermal equilibrium electron and hole concentration in a semiconductor is given by ne<\/sub>nh<\/sub> = n2<\/sup>r<\/sub>.<\/p>\n5. Energy band structure of Extrinsic semiconductors \nn-type semiconductor: \n \nIn n-type semiconductors, the donor energy level (ED<\/sub>) is slightly below conduction band.<\/p>\nP-type semiconductor: \n \nIn p-type semiconductors, the acceptor energy level (EA<\/sub>) lies slightly above valence bond.<\/p>\np-n Junction<\/span> \nA p-n junction is basic building block of semiconductor devices like diode, transistor, etc.<\/p>\n1. p-n junction formation: \nWhen pentavalent impurity is added to a part of p-type Si semiconductor wafer, we get both p region and n region in a single wafer. \nThe formation of p-n junction includes two processes.<\/p>\n (i) Diffusion: \nIn n type semiconductor, concentration of electrons is more than that of holes. In p-region, the hole concentration is more than electron concentration. Because of this concentration gradient, electrons diffuse from n side to p-side and holes diffuse from p-side to n-side during the formation of p-n junction. This produces diffusion current.<\/p>\n (ii) Drifting – Formation of Depletion region: \n \nWhen electrons diffuses from n to p, it leaves behind positively charged immobile donor ions on n-side. As electrons continue to diffuse from n to p, a layer of positive charge is developed on n- side.<\/p>\n Similarly when holes diffuse from p to n, it leaves behind negatively charged immobile ions on p side. As holes continue to diffuse from p to n, negative space charge region is developed on p side.<\/p>\n The positive space-charge region on n-side and negative space-charge region on p-side, is known as depletion region. This region contain only immobile ions.<\/p>\n 2. Barrier Potential: \nThe n-region losses electrons and p-region gains electrons. Because of this a potential is developed across the junction. This potential is called barrier potential.<\/p>\n Semiconductor Diodes<\/span> \nA semiconductor diode is a p-n junction provided with metallic contact at both ends to apply external voltage. \nThe symbol of p-n junction diode is given below. \n \nThe arrow shows conventional direction of current.<\/p>\n1. p-n junction diode under forward bias: \nWhen p-side of p-n junction diode is connected to positive terminal of the battery and n-side to the negative terminal it is said to be in forward biased. \n \nDue to the applied voltage, electrons of n-side get repelled by negative terminal of battery. Hence they cross depletion region and reach at p-side.<\/p>\n similarly the holes of p-side get repelled by positive terminal of battery and cross depletion region, reach n-side. The total forward current is sum of hole current and current due to electron.<\/p>\n 2. p-n junction diode under reverse bias: \nWhen p-side of p-n junction diode is connected to negative terminal of battery and n-side to the positive terminal, it is said to be in reversed biased. \n \nIn reverse bias the electrons of n-side and holes on p-side cannot cross the junction. But the minority carriers – holes on n-side and electrons on p-side drift across the junction and produce current. The reverse current is of the order micro ampere. \nNote: Junction width increases in reverse bias.<\/p>\n Breakdown Voltage (VBr<\/sub>): \nThe reverse current remains independent of bias voltage up to a critical reverse bias voltage called reverse break down voltage. At breakdown voltage, reverse current increases sharply.<\/p>\nV-I characteristics: \nTo study variation of current with voltage for p-n junction diode, it is connected to a battery through a rheostat. Rheostat is used to vary the biasing voltage. A milliammeter is connected in series with diode to study forward current.<\/p>\n To measure reverse current microammeter is used. A voltmeter is connected across diode to measure voltage. The current is measured for different values of volt and a graph (V-I) is plotted. \n \nIn forward bias, current first increases very slowly up to a certain value of bias voltage. After this voltage, diode current increases rapidly. This voltage is called Knee voltage or cut-in voltage or threshold voltage. (0.2v for Ge and 0.7v for Si). The diode offers low resistance in forward bias.<\/p>\n In reverse bias, current is very small. It remains almost constant up to break down voltage (called reverse saturation current). Afterthis voltage reverse current increases sharply. \nNote: \n(i) In forward bias, resistance is low compared to reverse bias. \n(ii) The dynamic resistance of diode is defined as ratio of change in voltage to change in current. \nrd<\/sub> = \\(\\frac{\\Delta v}{\\Delta l}\\)<\/p>\nApplication Of Junction Diode<\/span> \nDiode as a rectifier: \nThe process of converting AC into DC is known as Rectification. A p-n junction diode conducts current when it is forward biased, and does not conduct when it is reverse biased. This feature of the junction diode enables it to be used as rectifier.<\/p>\n1. Diode as half wave rectifier: \n \nCircuit details: \nA half wave rectifier consists of transformer, a diode and a load resistor RL<\/sub>. The primary coil of transformer is connected to a.c input and secondary is connected to RL<\/sub> through diode.<\/p>\nWorking: \nDuring the positive half cycle of the input a.c at secondary, the diode is forward biased and hence it conducts through RL<\/sub>. During negative half cycle of a.c at secondary, diode is reverse biased and does not conduct. Thus, we get +ve half cycle at the output. Hence the a.c input is converted into d.c output.<\/p>\n2. Full wave rectifier: \nCircuit details: \n \nFull wave rectifier consists of transformer, two diodes, and a load resistance RL<\/sub>. Input a.c signal is applied across the primary of the transformer. Secondary of the transformer is connected to D1<\/sub> and D2<\/sub>. The output is taken across RL<\/sub>.<\/p>\nWorking: \nDuring the +ve half cycle of the a.c signal at secondary, the diode D1<\/sub> is forward biased and D2<\/sub> is reverse biased. So that current flows through D1<\/sub> and RL<\/sub>.<\/p>\nDuring the negative half cycle of the a.c signal at secondary, the diode D1<\/sub> is reverse biased and D2<\/sub> is forward biased. So that current flows through D2<\/sub> and RL<\/sub>.<\/p>\nThus during both the half-cycles, the current flows through RL<\/sub> in the same direction. Thus we get a +ve voltage across RL<\/sub> for +ve and -ve input. This process is called full-wave rectification.<\/p>\nSpecial Purpose p-n Junction Diodes<\/span> \n1. Zener diode: \nZener diode is designed to operate under reverse bias in the breakdown region. It is used as a voltage regulator. The symbol for Zener diode is shown in figure. \n \nZener diode is heavily dopped. Hence depletion region is very thin. \nI-V characteristics of zener diode: \n \nThe l-V characteristics of a Zener diode is shown in above figure. At break down voltage, current increases rapidly. After breakdown, zener voltage remains constant. This property of the Zenerdiode is used for regulating supply voltages.<\/p>\nExplanation for large reverse current: \nReverse current is due to the flow of electrons (minority carriers) from p to n and holes from n to p. When the reverse bias voltage increases and becomes V = V2<\/sub> high electric field is developed. This high electric field can pull valence electrons from the atoms. These electrons account for high current.<\/p>\n1. (a) Zener diode as avoltage regulator Principle: \nIn reverse breakdown region, the voltage across the diode remains constant. \nCircuit details: \n<\/p>\n The Zener diode is connected to a fluctuating voltage supply through a resistor Rz<\/sub>. The output is taken across RL<\/sub>.<\/p>\nWorking: \nWhenever the supply voltage increases beyond the breakdown voltage, the current through zener increases (and also through Rz<\/sub>).<\/p>\nThus the voltage across Rz<\/sub> increases, by keeping the voltage drop across zenerdiode as a constant value. (This voltage drop across Rz<\/sub> is proportional to the input voltage).<\/p>\n2. Optoelectronic junction devices: \n(i) Photodiode: \nThe photodiode can be used as a photodetector to detect optical signals. \n \nIt is operated under reverse bias. When the photodiode is illuminated with light (photons) electron-hole pairs are generated. Due to electric field of the junction, electrons and holes are separated before they recombine.<\/p>\n The direction of the electric field is such that electrons reach n-side and holes reach p-side. Electrons collected on n-side and holes collected on p- side produce an emf. When an external load is connected, the current flows through the load. \nThe I-V characteristics of a photodiode: \n<\/p>\n (ii) Light-emitting diode [LED]: \nLED is heavily doped pn junction diode working under forward bias .Gallium Arsenide is used for making infrared LEDs.<\/p>\n Working: \nWhen the junction diode is forward biased, electrons and holes flow in opposite directions across junction. Some of the electrons and holes combine at junction and energy is produced in the form of light.<\/p>\n Uses: \nLEDs are used in remote controls, burglar alarm systems, optical communication, etc.<\/p>\n Advantages of LED over conventional incandescent lamps:<\/p>\n \n- Low operational voltage and less power.<\/li>\n
- Fast action and no warm-up time required.<\/li>\n
- The bandwidth of emitted light is 100 A\u00b0 to 500 A\u00b0 or in other words it is nearly (but not exactly) monochromatic.<\/li>\n
- Long life and ruggedness.<\/li>\n
- Fast on-off switching capability.<\/li>\n<\/ol>\n
3. Solar cell: \nSolar cell is junction diode used to convert solar energy into electrical energy. \nCircuit details: \n \nIts p-region is thin and transparent and is called emitter. The n-region is thick and is called base. Output is taken across RL<\/sub>.<\/p>\nWorking: \nWhen light falls on this layer, electrons from the n-region cross to the p-region and holes in the p-region cross in to the n-region. Thus a voltage is developed across RL<\/sub>. Solar cells are used to charge storage batteries during daytime. \nThe I-V characteristics of a solar cell: \n \nThe I-V characteristics of solar cell is drawn in the fourth quadrant of the coordinate axes. This is because a solar cell does not draw current but supplies the same to the load.<\/p>\nJunction Transistor<\/span> \n1. Transistor: structure and action \nTransistor is a three-layered doped semiconductor device. There are two types of transistors:<\/p>\n |