\nLead(II) carbonate<\/td>\n | White<\/td>\n | Brown<\/td>\n | Yellow<\/td>\n | Limewater turns milky.<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n Discussion:<\/strong><\/p>\n\n- Alkali metal carbonates such as sodium carbonate and potassium carbonate are stable to heat.<\/li>\n
- Most metal carbonates decompose on heating to produce metal oxides and liberate carbon dioxide gas.<\/li>\n
- The carbon dioxide gas forms a white precipitate with limewater, making the limewater milky.<\/li>\n<\/ol>\n
Conclusion:<\/strong> \nHeating a metal carbonate will decompose it into a metal oxide and liberate carbon dioxide. Group 1 metal carbonates are not decomposed by heat.<\/p>\nAction of Heat on Nitrate Salts<\/strong><\/h2>\n\n- Nitrate salts also undergo decomposition on heating.<\/li>\n
- Most metal nitrates<\/strong> decompose to produce a metal oxide<\/strong>, nitrogen dioxide<\/strong> and oxygen<\/strong>.
\n<\/li>\n- Sodium nitrate<\/strong> and potassium nitrate<\/strong> decompose to produce nitrite salts<\/strong> and oxygen<\/strong>.<\/li>\n
- Nitrogen dioxide is a brown gas. It is an acidic gas that turns moist blue litmus paper red. Hence, dissolving it in water produces a colourless acidic solution.
\n2NO2<\/sub>(g) + H2<\/sub>O(l) \u2192 HNO2<\/sub>(aq) + HNO3<\/sub>(aq)<\/li>\n- The colourless oxygen gas rekindles a glowing wooden splint.<\/li>\n<\/ol>\n
Table: Action of heat on nitrate salts<\/strong><\/p>\n\n\n\nNitrate salt<\/strong><\/td>\nAction of heat<\/strong><\/td>\n<\/tr>\n\nPotassium nitrate \nSodium nitrate<\/td>\n | Decompose to produce a nitrite salt and oxygen \n2KNO3<\/sub>(s) \u2192\u00a02KNO2<\/sub>(s) + O2<\/sub>(g) \n2NaNO3<\/sub>(s) \u2192\u00a02NaNO2<\/sub>(s) + O2<\/sub>(g)<\/td>\n<\/tr>\n\nCalcium nitrate \nMagnesium nitrate \nAluminium nitrate \nZinc nitrate \nIron(II) nitrate \nIron(III) nitrate \nLead(II) nitrate \nCopper(II) nitrate<\/td>\n | \n Decompose to produce metal oxide, nitrogen dioxide and oxygen \nMetal nitrate \u2192\u00a0metal oxide + nitrogen dioxide + oxygen \nFor example, \n2Cu(NO3<\/sub>)2<\/sub>(s) \u2192\u00a02CuO(s) + 4NO2<\/sub>(g) + O2<\/sub>(g)<\/p>\n<\/td>\n<\/tr>\n\nSilver nitrate<\/td>\n | Decomposes to produce metal, nitrogen dioxide and oxygen \n2AgNO3<\/sub>(s) \u2192\u00a02Ag(s) + 2NO2<\/sub> (g) + O2<\/sub>(g)<\/td>\n<\/tr>\n\nAmmonium nitrate<\/td>\n | Decomposes to produce nitrous oxide and water \nNH4<\/sub>NO3<\/sub>(s) \u2192\u00a0N2<\/sub>O(g) + 2H2<\/sub>O(l)<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\nAction of Heat on Nitrate Salts Experiment<\/strong><\/h2>\nAim:<\/strong> To investigate the action of heat on nitrate salts. \nMaterials:<\/strong> Sodium nitrate, magnesium nitrate, calcium nitrate, zinc nitrate, lead(II) nitrate, copper(II) nitrate, potassium nitrate, iron(III) nitrate, iron(II) nitrate, blue litmus paper and wooden splint. \nApparatus:<\/strong> Test tubes, tongs, spatula and Bunsen burner. \nProcedure:<\/strong><\/p>\n\n- About two spatulaful of copper(II) nitrate are placed in a test tube.<\/li>\n
- The colour of the nitrate salt is noted.<\/li>\n
- The nitrate salt is then heated strongly as shown in Figure.
\n<\/li>\n - The gases liberated are tested by
\n(a) lowering a glowing wooden splint into the test tube. \n(b) bringing a piece of moist blue litmus paper to the mouth of the test tube.<\/li>\n - The colour of the residue when it is hot and when it is cold are recorded.<\/li>\n
- Steps 1 to 5 are repeated using each of the nitrate salts listed in Table to replace the copper(II) nitrate.<\/li>\n<\/ol>\n
Observations:<\/strong><\/p>\n\n\n\nNitrate salt<\/strong><\/td>\nColour of salt before heating<\/strong><\/td>\nColour of residue<\/strong><\/td>\nTests for gases evolved<\/strong><\/td>\n<\/tr>\n\nHot<\/strong><\/td>\nCold<\/strong><\/td>\nColour of gas<\/strong><\/td>\nGlowing splint<\/strong><\/td>\nBlue litmus paper<\/strong><\/td>\n<\/tr>\n\nCopper(II) nitrate<\/td>\n | Blue<\/td>\n | Black<\/td>\n | Black<\/td>\n | Brown gas and colourless gas<\/td>\n | Rekindles<\/td>\n | Turns red<\/td>\n<\/tr>\n | \nSodium nitrate<\/td>\n | White<\/td>\n | White<\/td>\n | White<\/td>\n | Colourless<\/td>\n | Rekindles<\/td>\n | No change<\/td>\n<\/tr>\n | \nPotassium nitrate<\/td>\n | White<\/td>\n | White<\/td>\n | White<\/td>\n | Colourless<\/td>\n | Rekindles<\/td>\n | No change<\/td>\n<\/tr>\n | \nCalcium nitrate<\/td>\n | White<\/td>\n | White<\/td>\n | White<\/td>\n | Brown gas and colourless gas<\/td>\n | Rekindles<\/td>\n | Turns red<\/td>\n<\/tr>\n | \nMagnesium nitrate<\/td>\n | White<\/td>\n | White<\/td>\n | White<\/td>\n | Brown gas and colourless gas<\/td>\n | Rekindles<\/td>\n | Turns red<\/td>\n<\/tr>\n | \nZinc nitrate<\/td>\n | White<\/td>\n | Yellow<\/td>\n | White<\/td>\n | Brown gas and colourless gas<\/td>\n | Rekindles<\/td>\n | Turns red<\/td>\n<\/tr>\n | \nIron(II) nitrate<\/td>\n | Green<\/td>\n | Black<\/td>\n | Black<\/td>\n | Brown gas and colourless gas<\/td>\n | Rekindles<\/td>\n | Turns red<\/td>\n<\/tr>\n | \nIron(III) nitrate<\/td>\n | Brown<\/td>\n | Brown<\/td>\n | Brown<\/td>\n | Brown gas and colourless gas<\/td>\n | Rekindles<\/td>\n | Turns red<\/td>\n<\/tr>\n | \nLead(II) nitrate<\/td>\n | White<\/td>\n | Brown<\/td>\n | Yellow<\/td>\n | Brown gas and colourless gas<\/td>\n | Rekindles<\/td>\n | Turns red<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n Discussion:<\/strong><\/p>\n\n- When nitrate salts are heated, they decompose to liberate nitrogen dioxide and oxygen.<\/li>\n
- Only sodium nitrate and potassium nitrate decompose to liberate oxygen.<\/li>\n
- Nitrogen dioxide is a brown gas that turns moist blue litmus paper red.<\/li>\n
- Oxygen is a colourless gas that relights a glowing wooden splint.<\/li>\n<\/ol>\n
Conclusion:<\/strong> \nMost metal nitrates decompose to produce a metal oxide, nitrogen dioxide and oxygen except sodium nitrate and potassium nitrate which decompose to produce nitrite salts and oxygen.<\/p>\nAction of Heat on Sulphate Salts<\/strong><\/h2>\n\n- The normal sulphate salts are more stable to heat compared to the carbonates and nitrates.<\/li>\n
- Group 1 metal sulphates such as sodium sulphate and potassium sulphate do not decompose on heating. Group 2 metal sulphates such as calcium sulphate also do not decompose when heated.<\/li>\n
- The sulphates of heavy metals are decomposed into metal oxides and sulphur trioxide when heated.
\n<\/li>\n - Sulphur trioxide is a typical acidic oxide and dissolves in water to form sulphuric acid.
\nSO3<\/sub>(g) + H2<\/sub>O(l) \u2192 H2<\/sub>SO4<\/sub>(aq)<\/li>\n- An exceptional case is iron(II) sulphate because it also forms sulphur dioxide gas.
\n2FeSO4<\/sub>(s) \u2192 Fe2<\/sub>O3<\/sub>(s) + SO3<\/sub>(g) + SO2<\/sub>(g) \nThe green crystals of iron(II) sulphate turn into a brown solid of iron(III) oxide.<\/li>\n- Ammonium sulphate sublimes when first heated. Further heating decomposes the salt into ammonia and hydrogen sulphate.
\n(NH4<\/sub>)2<\/sub>SO4<\/sub>(S) – 2NH3<\/sub>(g) + H2<\/sub>SO4<\/sub>(g)<\/li>\n<\/ol>\nAction of Heat on Chloride Salts<\/strong><\/h2>\n\n- Chloride salts are stable to heat except ammonium chloride<\/strong>.<\/li>\n
- Initial heating of ammonium chloride causes the salt to sublime.
\nNH4<\/sub>Cl(S) \u2192 NH4<\/sub>Cl(g)<\/li>\n- On further heating, decomposition takes place to produce ammonia<\/strong> and hydrogen chloride<\/strong>.
\nNH4<\/sub>Cl(g) \u2192 NH3<\/sub>(g) + HCl(g)<\/li>\n- When ammonium chloride is heated in a test tube, the lighter ammonia gas will emerge first and turn a piece of moist red litmus paper blue. Hydrogen chloride, coming up next, will change the litmus paper from blue back to red.
\n<\/li>\n<\/ol>\nIdentification of salts by action of heat<\/strong><\/h2>\n\n- When a salt is heated strongly, it may decompose. One or more gases may be liberated.<\/li>\n
- Each gas can be identified by\n
\n- noting its colour.<\/li>\n
- testing it with moist blue or red litmus paper.<\/li>\n
- testing it with limewater.<\/li>\n
- testing it with glowing wooden splint.<\/li>\n
- testing it with acidified potassium dichromate(VI) solution or acidified potassium manganate(VII) solution.<\/li>\n<\/ul>\n<\/li>\n
- The colour of the residue when hot and cold must be noted to help in the identification of the salt.<\/li>\n
- The following table shows how to identify salts P, Q, R, S and T through gases liberated by the action of heat.<\/li>\n<\/ol>\n
\n\n\nTest<\/strong><\/td>\nObservation<\/strong><\/td>\nInference<\/strong><\/td>\n<\/tr>\n\nHeat P in a test tube. Identify the gas\/gases given off.<\/td>\n | \n\n- A colourless gas is liberated.<\/li>\n
- It forms a white precipitate with limewater, i.e. limewater turns milky.<\/li>\n<\/ul>\n<\/td>\n
\n\n- Carbon dioxide gas, CO2<\/sub>, is produced.<\/li>\n
- Carbonate ion, CO2<\/sub>2-<\/sup>, is present.<\/li>\n
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