{"id":13178,"date":"2022-11-18T16:00:43","date_gmt":"2022-11-18T10:30:43","guid":{"rendered":"https:\/\/www.aplustopper.com\/?p=13178"},"modified":"2022-11-19T16:31:45","modified_gmt":"2022-11-19T11:01:45","slug":"qualitative-analysis-salts","status":"publish","type":"post","link":"https:\/\/www.aplustopper.com\/qualitative-analysis-salts\/","title":{"rendered":"Qualitative Analysis of Salts"},"content":{"rendered":"
What is qualitative analysis?<\/strong><\/p>\n People also ask<\/strong><\/p>\n Table lists the colours of some common salts.<\/strong><\/p>\n Table shows the solubility of some common compounds.<\/strong><\/p>\n Example:\u00a0<\/strong>Preliminary examination of solid X gave the following observations. Identify solid X. Explain your answer.<\/p>\n Solution:<\/strong><\/p>\n Test for gases<\/strong><\/p>\n Observation:<\/strong><\/p>\n Observation:<\/strong><\/p>\n Observation:<\/strong><\/p>\n Observation:<\/strong><\/p>\n Observation:<\/strong><\/p>\n <\/p>\n Observation:<\/strong><\/p>\n <\/p>\n Observation:<\/strong><\/p>\n <\/p>\n Observation:<\/strong><\/p>\n\n
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Examining the colour and solubility of salts in water<\/strong><\/h2>\n
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\n(a) Iron(II) ions, nickel(II) ions and chromium(III) ions dissolve in water to produce green solutions.
\n(b) Sodium chloride and potassium carbonate are white solids. Both solids dissolve in water to produce colourless solutions.<\/li>\n\n\n
\n Salt<\/strong><\/td>\n Colour<\/strong><\/td>\n<\/tr>\n \n Solid<\/strong><\/td>\n Aqueous solution<\/strong><\/td>\n<\/tr>\n \n Potassium salts
\nSodium salts
\nAmmonium salts
\nAluminium salts
\nCalcium salts
\nLead(ll) salts
\nZinc salts
\n(with colourless anions)<\/td>\nWhite<\/td>\n Colourless<\/td>\n<\/tr>\n \n Carbonate salts
\nChloride salts
\nNitrate salts
\nSulphate salts
\n(with colourless cations)<\/td>\nWhite<\/td>\n Colourless<\/td>\n<\/tr>\n \n Iron(II) salts:<\/strong>
\nIron(II) chloride Iron(II) nitrate iron(II) sulphate<\/td>\nGreen<\/td>\n Green<\/td>\n<\/tr>\n \n Iron(III) salts:<\/strong>
\nIron(III) chloride
\nIron(III) nitrate
\nIron(III) sulphate<\/td>\nBrown<\/td>\n Brown<\/td>\n<\/tr>\n \n Copper(II) salts:<\/strong>
\nCopper(II) chloride
\nCopper(II) nitrate
\nCopper(II) sulphate<\/td>\nBlue<\/td>\n Blue<\/td>\n<\/tr>\n \n \u00a0Copper(II) carbonate<\/td>\n \u00a0Green<\/td>\n (Insoluble)<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n \n\n
\n Compound<\/strong><\/td>\n Solubility in water<\/strong><\/td>\n<\/tr>\n \n Sodium, potassium and ammonium salts<\/td>\n All are soluble<\/td>\n<\/tr>\n \n Nitrate salts<\/td>\n All are soluble<\/td>\n<\/tr>\n \n Ethanoate salts<\/td>\n All are soluble<\/td>\n<\/tr>\n \n Chloride salts<\/td>\n All are soluble except AgCl, HgCl and PbCl2<\/sub><\/td>\n<\/tr>\n \n Sulphate salts<\/td>\n All are soluble except BaSO4<\/sub>, PbSO4<\/sub> and CaSO4<\/sub><\/td>\n<\/tr>\n \n Carbonate salts<\/td>\n All are insoluble except Na2<\/sub>CO3<\/sub>, K2CO3<\/sub> and (NH4<\/sub>)2<\/sub>CO3<\/sub><\/td>\n<\/tr>\n \n Metal oxides<\/td>\n All are insoluble except Na2<\/sub>O, K2<\/sub>O and CaO (slightly soluble)<\/td>\n<\/tr>\n \n Metal hydroxides<\/td>\n All are insoluble except NaOH, KOH and Ba(OH)2<\/sub><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n \n
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\n(a) salts are heated.
\n(b) salts are reacted with acids or alkalis.<\/li>\n
\n(a) Heating a carbonate salt produces carbon dioxide gas.
\n(b) Reacting a metal with dilute acids produces hydrogen gas.<\/li>\n\n\n
\n Gas<\/strong><\/td>\n Characteristic<\/strong><\/td>\n<\/tr>\n \n Ammonia
\n<\/strong>Method:<\/strong><\/p>\n\n
\n<\/li>\n<\/ul>\n\n
\n \n
\nForms dense white fumes with hydrogen chloride Produced by heating a mixture of ammonium salt and alkali
\nNH4<\/sub>Cl(s) + NaOH(aq) \u2192\u00a0NaCl(aq) + NH3<\/sub>(g) + H2<\/sub>O(l)<\/li>\n<\/ul>\n<\/td>\n<\/tr>\n\n Oxygen
\nMethod: <\/strong><\/p>\n\n
\n<\/li>\n<\/ul>\n\n
\n \n
\n2KClO3<\/sub>(s) \u2192\u00a02KCl(s) + 3O2<\/sub>(g)
\n2Pb(NO3<\/sub>)2<\/sub>(s) \u2192\u00a02PbO(s) + 4NO2<\/sub>(g) + O2<\/sub>(g)<\/li>\n<\/ul>\n<\/td>\n<\/tr>\n\n Carbon dioxide
\nMethod:<\/strong><\/p>\n\n
\n<\/li>\n<\/ul>\n\n
\n \n
\nCaCO3<\/sub>(s) \u2192 CaO(s) + C02(g)
\nCaCO3<\/sub>(s) + 2HCl(aq) \u2192\u00a0CaCl2<\/sub>(aq) + H2<\/sub>O(l) + CO2<\/sub>(g)<\/li>\n<\/ul>\n<\/td>\n<\/tr>\n\n Hydrogen
\n<\/strong>Method:<\/strong><\/p>\n\n
\n<\/li>\n<\/ul>\n\n
\n \n
\nMg(s) + 2HCl(aq) \u2192\u00a0MgCl2<\/sub>(aq) + H2<\/sub>(g)<\/li>\n<\/ul>\n<\/td>\n<\/tr>\n\n Chlorine
\n<\/strong>Method:<\/strong><\/p>\n\n
\n<\/li>\n<\/ul>\n\n
\n \n
\nMnO2<\/sub>(s) + 4HCl(aq) \u2192\u00a0MnCl2<\/sub>(aq) + Cl2<\/sub>(g) + 2H2<\/sub>0(l)<\/li>\n<\/ul>\n<\/td>\n<\/tr>\n\n Sulphur dioxide
\n<\/strong>Method:<\/strong><\/p>\n\n
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\n \n
\nNa2<\/sub>SO3<\/sub>(s) + 2HCl(aq) \u2192\u00a02NaCl(aq) + H2<\/sub>O(l) + SO2<\/sub>(g)<\/li>\n<\/ul>\n<\/td>\n<\/tr>\n\n Hydrogen chloride
\n<\/strong>Method:<\/strong><\/p>\n\n
\n
\n \n
\nH2<\/sub>SO4<\/sub>(aq) + NaCl(s) \u2192\u00a0NaHSO4<\/sub>(aq) + HCl(g)<\/li>\n<\/ul>\n<\/td>\n<\/tr>\n\n Nitrogen dioxide
\n<\/strong>Method:<\/strong><\/p>\n\n
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\n \n
\n2Cu(NO3<\/sub>)O2<\/sub>(s) \u2192\u00a02CuO(s) + 4NO2<\/sub>(g) + O